Bis[4-chloro-2-(iminomethyl)phenolato]copper(II) methanol disolvate
نویسنده
چکیده
The title compound, [Cu(C(7)H(5)ClNO)(2)]·2CH(3)OH, possesses crystallographic twofold symmetry, with the twofold axis passing through the central Cu(II) ion. The metal centre is coordinated by two O atoms and two N atoms from two symmetry-related Schiff base ligands, forming a slightly distorted cis-CuN(2)O(2) square-planar geometry. The complex mol-ecules are linked via the solvent methanol mol-ecules by O-H⋯O and N-H⋯O hydrogen bonds, leading to the formation of chains along the b axis.
منابع مشابه
Bis[4-chloro-2-(iminomethyl)phenolato]copper(II)
In the title mononuclear copper(II) complex, [Cu(C(7)H(5)ClNO)(2)], the Cu atom, situated on an inversion center, is four-coordinated, in a slightly distorted square-planar geometry, by the N- and O-donor atoms of two symmetry-related 4-chloro-2-(imino-meth-yl)phenolate Schiff base ligands.
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متن کاملBis{(E)-4-bromo-2-[(2-chloro-3-pyridyl)iminomethyl]phenolato-κ2 N,O}copper(II)
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009